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UPCAT ChemistryChemical Equilibrium & REDOXSlides

Slide deck for UPCAT Chemistry — Chemical Equilibrium & REDOX. These slides are built for quick visual review, highlighting the key concepts, formulas, and question patterns from this chapter of the UPCAT 2026 syllabus.

Exam context

For the University of the Philippines College Admission Test, University of the Philippines tests Chemistry under a "Core" label, with Chemical Equilibrium & REDOX in the 7th slot across 7 chapters. UPCAT candidates must clear the UPG ≤ 2.2 typical cut on the 2026 paper, which draws about 20 Chemistry questions. Date to watch: Mid-2026 (announced by UP Admissions).

Chemical Equilibrium & REDOX - Slides

This chapter explores two fundamental concepts in chemistry: chemical equilibrium and oxidation-reduction (REDOX) reactions. Chemical equilibrium describes the dynamic balance between forward and reverse reactions, while REDOX reactions involve the transfer of electrons between substances. These concepts are essential for understanding many chemical processes in nature and industry.

Slides

Chemical Equilibrium & REDOX Overview

This chapter covers two interconnected areas of chemistry that help us understand how reactions proceed and reach balance, as well as how electrons move between atoms and molecules.

Notes

Introduction to the two major topics covered in this chapter

Topic

Chapter Overview

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mindmap root((Chemical Equilibrium & REDOX)) Chemical Equilibrium Dynamic Balance Forward and Reverse Rates Closed System Constant Concentrations REDOX Reactions Electron Transfer Oxidation Loss Reduction Gain Oxidizing Agent Reducing Agent Applications Industrial Processes Biological Systems Energy Production

Type

mermaid_mindmap

Description

Mind map showing the main concepts of chemical equilibrium and REDOX reactions with their key characteristics and applications

What is Chemical Equilibrium?

Chemical equilibrium occurs when a reversible reaction reaches a point where the rate of products forming equals the rate of products breaking down back into reactants.

Notes

Emphasize that equilibrium is dynamic - reactions continue but with no net change

Topic

Chemical Equilibrium Definition

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Mermaid Diagram

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flowchart TD A[Reactants] -->|Forward Rate| B[Products] B -->|Reverse Rate| A C[At Equilibrium] --> D[Forward Rate = Reverse Rate] D --> E[Concentrations Constant] E --> F[Dynamic Process Continues]

Type

mermaid_flowchart

Description

Flowchart showing how chemical equilibrium is established when forward and reverse reaction rates become equal

Characteristics of Chemical Equilibrium

These five key characteristics define what makes a chemical system at equilibrium and how it behaves under different conditions.

Notes

Highlight that equilibrium can be reached from either reactants or products

Topic

Equilibrium Characteristics

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stateDiagram-v2 [*] --> ReactantsOnly ReactantsOnly --> ForwardDominant: Reaction starts ForwardDominant --> Equilibrium: Rates balance ProductsOnly --> ReverseDominant: Reverse reaction ReverseDominant --> Equilibrium: Rates balance Equilibrium --> ShiftedEquilibrium: Condition change ShiftedEquilibrium --> Equilibrium: New balance

Type

mermaid_stateDiagram

Description

State diagram showing how chemical systems reach equilibrium from different starting points and respond to changes

Thermochemistry and Energy

Thermochemistry studies energy changes during chemical reactions, which helps us understand why reactions occur and reach equilibrium.

Notes

Connect energy concepts to equilibrium - systems seek lowest energy state

Topic

Thermochemistry

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flowchart TD A[Energy in Chemical Systems] --> B[Potential Energy] A --> C[Kinetic Energy] B --> D[Stored Energy] C --> E[Motion Energy] E --> F[KE = 1/2 mv²] A --> G[Energy Transfer] G --> H[Heat q] G --> I[Work w] H --> J[ΔU = q + w] I --> J

Type

mermaid_flowchart

Description

Flowchart showing different types of energy in chemical systems and how energy transfer occurs

Introduction to REDOX Reactions

REDOX reactions are a major class of chemical reactions where electrons are transferred from one substance to another, resulting in changes in oxidation numbers.

Notes

Emphasize that REDOX is about electron movement, not just oxygen addition

Topic

REDOX Introduction

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flowchart TD A[REDOX Reactions] --> B[Electron Transfer] B --> C[Oxidation] B --> D[Reduction] C --> E[Loss of Electrons] D --> F[Gain of Electrons] A --> G[Applications] G --> H[Combustion] G --> I[Electricity] G --> J[Cellular Energy]

Type

mermaid_flowchart

Description

Flowchart showing the fundamental concept of REDOX reactions as electron transfer processes with various applications

Oxidation and Reduction Definitions

Understanding these definitions is crucial for identifying and analyzing REDOX reactions. The agents undergo the opposite process from what they cause.

Notes

Use OIL RIG memory aid to help students remember electron transfer direction

Topic

REDOX Definitions

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6

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flowchart TD A[REDOX Process] --> B[Oxidation] A --> C[Reduction] B --> D[Loss of Electrons] B --> E[Oxidation Number Increases] C --> F[Gain of Electrons] C --> G[Oxidation Number Decreases] H[Oxidizing Agent] --> I[Causes Oxidation] I --> J[Gets Reduced] K[Reducing Agent] --> L[Causes Reduction] L --> M[Gets Oxidized]

Type

mermaid_flowchart

Description

Flowchart illustrating the definitions of oxidation, reduction, and the roles of oxidizing and reducing agents

Oxidation Number Rules (Part 1)

Oxidation numbers help track electron transfer in REDOX reactions. These rules provide a systematic way to assign oxidation numbers to atoms in compounds.

Notes

Focus on the most common and important rules first

Topic

Oxidation Number Rules

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7

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Oxidation Number Rules (Part 2)

These additional rules cover halogens and the important constraint that oxidation numbers must sum to the overall charge of the molecule or ion.

Notes

Emphasize checking that oxidation numbers sum correctly

Topic

Oxidation Number Rules

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flowchart TD A[Assign Oxidation Numbers] --> B[Apply Rules 1-6] B --> C[Calculate Sum] C --> D{Neutral Molecule?} D -->|Yes| E[Sum = 0] D -->|No| F[Sum = Ion Charge] E --> G[Check Answer] F --> G G --> H[Identify REDOX Changes]

Type

mermaid_flowchart

Description

Flowchart showing the step-by-step process for assigning oxidation numbers and checking the results

Oxidation Number Examples

Working through examples helps students master the systematic approach to finding oxidation numbers, especially for less obvious cases like nitrogen in nitrate.

Notes

Show step-by-step calculation for complex examples

Topic

Oxidation Number Examples

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mermaid

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9

Mermaid Diagram

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flowchart TD A[KNO₃] --> B[K = +1] A --> C[O = -2] A --> D[N = ?] E[Sum must equal 0] --> F[+1 + N + 3(-2) = 0] F --> G[+1 + N - 6 = 0] G --> H[N = +5] B --> E C --> E D --> E

Type

mermaid_flowchart

Description

Flowchart showing the calculation process for determining the oxidation number of nitrogen in KNO₃

Identifying Oxidizing and Reducing Agents

By tracking changes in oxidation numbers, we can identify which species are oxidized or reduced and determine the oxidizing and reducing agents.

Notes

Emphasize that the agent does the opposite of what it causes

Topic

REDOX Agents

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Mermaid Diagram

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flowchart TD A[2H₂ + O₂ → 2H₂O] --> B[Assign Oxidation Numbers] B --> C[H₂: 0 → +1] B --> D[O₂: 0 → -2] C --> E[H₂ Oxidized] D --> F[O₂ Reduced] E --> G[H₂ is Reducing Agent] F --> H[O₂ is Oxidizing Agent]

Type

mermaid_flowchart

Description

Flowchart showing how to identify oxidizing and reducing agents by comparing oxidation number changes

Balancing REDOX Equations - Overview

Balancing REDOX equations requires special techniques because we must account for electron transfer in addition to mass balance.

Notes

Introduce both methods before diving into details

Topic

REDOX Balancing Methods

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flowchart TD A[REDOX Equation] --> B{Choose Method} B -->|Simpler| C[Oxidation Number Method] B -->|Complex| D[Half-Reaction Method] C --> E[Balance electrons] D --> E E --> F[Complete balancing] F --> G[Check mass and charge]

Type

mermaid_flowchart

Description

Flowchart showing the decision process for choosing a REDOX balancing method

Oxidation Number Method - Steps

The oxidation number method is systematic and works well for many REDOX equations. It focuses on electron changes to determine balancing coefficients.

Notes

Walk through each step systematically with the example

Topic

Oxidation Number Method

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mermaid

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Mermaid Diagram

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flowchart TD A[Unbalanced REDOX] --> B[Assign O.N.] B --> C[Identify Changes] C --> D[Count Electrons] D --> E[Balance Electrons] E --> F[Add Coefficients] F --> G[Complete Balance] G --> H[Check Final Equation]

Type

mermaid_flowchart

Description

Step-by-step flowchart for the oxidation number method of balancing REDOX equations

Oxidation Number Method - Example

This example demonstrates the complete process, showing how electron balance determines the coefficients needed for the balanced equation.

Notes

Emphasize how electron balance determines coefficients

Topic

Oxidation Number Method Example

Slide Id

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sequenceDiagram participant Al as Aluminum participant H as Hydrogen Al->>H: Transfers 6 electrons Note over Al: Al → Al³⁺ + 3e⁻ Note over Al: (2 Al atoms = 6e⁻) Note over H: H⁺ + e⁻ → H Note over H: (6 H⁺ = 6e⁻) H-->>Al: Balanced electron transfer

Type

mermaid_sequence

Description

Sequence diagram showing electron transfer between aluminum and hydrogen in the balanced REDOX reaction

Half-Reaction Method - Steps

The half-reaction method is more systematic for complex REDOX equations, especially in acidic or basic solutions. It handles each half-reaction separately before combining.

Notes

Emphasize the systematic approach of balancing each half separately

Topic

Half-Reaction Method

Slide Id

S14

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mermaid

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Mermaid Diagram

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flowchart TD A[REDOX Equation] --> B[Separate Half-Reactions] B --> C[Oxidation Half] B --> D[Reduction Half] C --> E[Balance Atoms] D --> E E --> F[Balance Charge] F --> G[Equalize Electrons] G --> H[Add Half-Reactions] H --> I[Final Balanced Equation]

Type

mermaid_flowchart

Description

Flowchart showing the systematic steps of the half-reaction method for balancing REDOX equations

Half-Reaction Method - Detailed Example

This complete example shows how to balance atoms (Cl, I, O, H) and charges in each half-reaction, then combine them with proper electron balance.

Notes

Show complete balancing process step by step

Topic

Half-Reaction Method Example

Slide Id

S15

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mermaid

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15

Mermaid Diagram

Code

sequenceDiagram participant ClO3 as ClO₃⁻ participant I as I⁻ ClO3->>I: Accepts 6 electrons Note over ClO3: ClO₃⁻ + 6H⁺ + 6e⁻ → Cl⁻ Note over I: 6I⁻ → 3I₂ + 6e⁻ I-->>ClO3: Provides 6 electrons Note over ClO3, I: Balanced: 6e⁻ transferred

Type

mermaid_sequence

Description

Sequence diagram illustrating the electron transfer in the balanced half-reactions between chlorate and iodide ions

Applications of Chemical Equilibrium

Chemical equilibrium principles are applied in many real-world situations, from industrial manufacturing to biological processes that sustain life.

Notes

Connect equilibrium concepts to real-world applications students can relate to

Topic

Equilibrium Applications

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S16

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mermaid

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Mermaid Diagram

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mindmap root((Equilibrium Applications)) Industrial Haber Process Contact Process Petroleum Refining Environmental Ocean CO2 Atmospheric Chemistry Acid Rain Biological Oxygen Transport Enzyme Function Buffer Systems Laboratory pH Control Solubility Analytical Chemistry

Type

mermaid_mindmap

Description

Mind map showing the diverse applications of chemical equilibrium in industrial, environmental, biological, and laboratory settings

Applications of REDOX Reactions

REDOX reactions are fundamental to energy conversion, metal production, life processes, and many industrial applications that affect daily life.

Notes

Highlight how REDOX reactions are essential to modern technology and life

Topic

REDOX Applications

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mermaid

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Mermaid Diagram

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mindmap root((REDOX Applications)) Energy Batteries Fuel Cells Solar Cells Combustion Biology Respiration Photosynthesis Metabolism Industry Metal Extraction Electroplating Bleaching Environment Water Treatment Corrosion Pollution Control

Type

mermaid_mindmap

Description

Mind map illustrating the wide range of REDOX reaction applications in energy, biology, industry, and environmental processes

Key Formulas and Relationships

These fundamental formulas and relationships are essential tools for solving problems involving chemical equilibrium and REDOX reactions.

Notes

Provide clear formula reference for problem-solving

Topic

Key Formulas

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18

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Problem-Solving Strategy

A systematic approach to problem-solving helps students tackle complex equilibrium and REDOX problems with confidence.

Notes

Emphasize systematic approach and checking answers

Topic

Problem-Solving Strategy

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Mermaid Diagram

Code

flowchart TD A[Chemistry Problem] --> B{Type?} B -->|Equilibrium| C[Identify System] B -->|REDOX| D[Assign O.N.] C --> E[Analyze Changes] D --> F[Identify Agents] E --> G[Apply Principles] F --> H[Balance Equation] G --> I[Check Answer] H --> I I --> J[Verify Logic]

Type

mermaid_flowchart

Description

Problem-solving flowchart showing the systematic approach to tackling equilibrium and REDOX chemistry problems

Chapter Summary

This chapter covered fundamental concepts that explain how chemical reactions reach balance and how electrons move between atoms, forming the basis for understanding many chemical processes.

Notes

Comprehensive review of all major topics covered

Topic

Chapter Summary

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mindmap root((Chapter Summary)) Chemical Equilibrium Dynamic Balance Closed Systems Rate Equality Applications REDOX Reactions Electron Transfer Oxidation Numbers Balancing Methods Real World Uses Key Skills Problem Solving Equation Balancing Agent Identification

Type

mermaid_mindmap

Description

Mind map summarizing the key concepts, principles, and skills covered in the Chemical Equilibrium and REDOX chapter

References

  • CET 2026 COMPREHENSIVE LECTURE NOTES — Science.pdf
  • General Chemistry Principles and Modern Applications
  • Philippine Science High School Chemistry Curriculum
  • UPCAT Science Review Materials

In summary

Chemical equilibrium and REDOX reactions are fundamental concepts in chemistry that explain how reactions reach balance and how electrons transfer between substances. Understanding these concepts provides insight into countless natural and industrial processes, from the oxygen transport in our blood to the batteries that power our devices. Mastering oxidation numbers, balancing techniques, and the principles of equilibrium will provide a strong foundation for advanced chemistry studies and practical applications in science and technology.

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